Entropy-controlled supramolecular photochirogenesis: enantiodifferentiating Z-E photoisomerization of cyclooctene included and sensitized by permethylated 6-O-benzoyl-beta-cyclodextrin

摘要

In contrast to the photosensitization with a non-methylated analogue, supramolecular photochirogenesis with a novel permethylated mono (6-O-benzoyl)-beta-cyclodextrin exhibited a critical dependence of the product's enantiomeric excess upon temperature, and possessed a large differential entropy of activation (-11 J K-1 mol(-1)) for which the flexible host skeleton is likely to be responsible.