New catalytic route to functionalized vinylboronates

摘要

Vinylsubstituted boronates i.e.vinyldioxaborolane and vinyl-dioxaborinane react regioselectively with olefins in the presence of RuHCl(COXPCy_3)_2 with the formation of functionalized vinylboron derivatives.The reaction opens a new catalytic route for preparation of organoboranes.