First mixed hydrazide/hydroxylamide metal aggregates

摘要

The first organometallic clusters of mixed hydrazide/hydroxylamide clusters of zinc, [Zn(MeZn)(4)(HNNMe2)(2)(ONEt2)(4)] and {Zn(EtZn)(4)[HNN(CH2)(5)](2)(ONEt2)(4)} were synthesized in one-pot synthesis protocols from dialkylzinc solutions, substituted hydrazines and N,N-diethylhydroxylamine; competing for the Zn atoms, the different binding properties of hydrazide and hydroxylamide ligands in these heteroleptic clusters are discussed.