The first route to large pore metal phosphonates

Groves JA; Miller SR; Warrender SJ; Mellot-Draznieks C; Lightfoot P; Wright PA

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The first route to large pore metal phosphonates

机译：大孔金属膦酸酯的第一条途径

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摘要

The first large pore ( free diameter >7 angstrom) metal phosphonates have been prepared as divalent metal N,N'-piperazinebis( methylenephosphonate)s that possess pores greater than ca. 10 angstrom in free diameter, are stable up to 400 degrees C and offer a route to chiral adsorbents and catalysts.

机译：已经制备了第一大孔（自由直径＞ 7埃）金属膦酸酯，其为具有大于约1μm的孔的二价金属N，N′-哌嗪双（亚甲基膦酸酯）。自由直径为10埃，在高达400摄氏度的温度下稳定，并提供了通往手性吸附剂和催化剂的途径。

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来源
《Chemical Communications》 |2006年第31期|p. 3305-3307|共3页
作者
Groves JA; Miller SR; Warrender SJ; Mellot-Draznieks C; Lightfoot P; Wright PA;
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作者单位

Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland;

Royal Inst Great Britain, Davy Faraday Labs, London W1X 4BS, England;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
LINED UNIDIMENSIONAL CHANNELS; ALUMINUM METHYLPHOSPHONATE; CRYSTAL-STRUCTURES; ORGANIC FRAMEWORK; ALMEPO-ALPHA; ADSORPTION; INCLUSION; CAVITIES; POLYMER; DESIGN;

机译：带衬里的单维通道;甲基膦酸铝;晶体结构;有机框架;阿尔法-铝;吸附;包容;腔;聚合物;设计;

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1. A route to functionalised pores in coordination polymers via mixed phosphonate and amino-triazole linkers [J] . Vaidhyanathan R., Liang J., Iremonger S.S., Supramolecular chemistry . 2011,第3a4期

机译：通过膦酸酯和氨基-三唑混合接头通往配位聚合物中官能化孔的途径
2. A route to functionalised pores in coordination polymers via mixed phosphonate and amino-triazole linkers [J] . Ramanathan Vaidhyanathan, George K.H. Shimizu Supramolecular Chemistry . 2011,第3a4期

机译：通过膦酸酯和氨基-三唑混合接头通往配位聚合物中功能化孔的途径
3. Diffusion of Carbon Dioxide and Nitrogen in the Small‐Pore Titanium Bis(phosphonate) Metal–Organic Framework MIL‐91 (Ti): A Combination of Quasielastic Neutron Scattering Measurements and Molecular Dynamics Simulations [J] . Pillai Renjith Sasimohanan, Jobic Hervé, Koza Michael Marek, Chemphyschem: A European journal of chemical physics and physical chemistry . 2017,第19期

机译：二氧化碳和氮气在小孔隙钛（膦酸盐）金属 - 有机框架MIL-91（TI）中的扩散：拟塑性中子散射测量和分子动力学模拟的组合
4. The Relation Between Barite Inhibition by Phosphonate Scale Inhibitors and the Structures of Phosphonate-Metal Complexes [C] . S.S. Shaw, T.D. Welton, K.S. Sorbie Society of Plastics Engineers International Conference and Exhibition on Oilfield Scale . 2012

机译：膦酸盐尺度抑制剂与膦酸盐 - 金属配合物结构之间的关系
5. Organic structural influences on metal oxide systems: Vanadium phosphates, vanadium phosphonates, and molybdenum phosphonates. [D] . Finn, Robert Clyde. 2001

机译：有机结构对金属氧化物系统的影响：磷酸钒，膦酸钒和膦酸钼。
6. Different Formation Routes of Pore Structure in Aluminum Powder Metallurgy Alloy [O] . Jana Bidulská, Róbert Bidulský, Marco Actis Grande, 2019

机译：铝粉末冶金合金中孔结构的不同形成途径
7. Diffusion of Carbon Dioxide and Nitrogen in the Small‐Pore Titanium Bis(phosphonate) Metal–Organic Framework MIL‐91 (Ti): A Combination of Quasielastic Neutron Scattering Measurements and Molecular Dynamics Simulations [O] . Renjith Sasimohanan Pillai, Hervé Jobic, Michael Marek Koza, 2017

机译：二氧化碳和氮气在小孔隙钛（膦酸盐）金属 - 有机框架MIL-91（TI）中的扩散：拟塑性中子散射测量和分子动力学模拟的组合

The first route to large pore metal phosphonates

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