NO-disproportionation, promoted by Pd-cluster: formation and X-ray structure of Pd_8(μ-CO)_4(μ-OOCCMe_3)_8[μ-N(=O)O-]_4

摘要

Interaction of Pd-clusters [Pd(CO)(OCOR)]_n with NO was investigated, these Pd-clusters were found to promote the NO disproportionation into N_2 and NO_2~- in mild conditions; an eight-nuclear palladium cluster Pd_8(μ-CO)_4(μ-OOCCMe_3)_8-(μ-NO_2)_4 with a new type of structure and an uncommon set of ligands was characterized by X-ray diffraction analysis.