New trifluoromethylated derivatives of [60]fullerene, C_(60)(CF_3)_n with n = 12 and 14

Nadezhda A. Omelyanyuk; Alexey A. Goryunkov; Nadezhda B. Tamm; Stanislav M. Avdoshenko; Ilya N. Ioffe; Lev N. Sidorov; Erhard Kemnitz; Sergey I. Troyanov

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New trifluoromethylated derivatives of [60]fullerene, C_(60)(CF_3)_n with n = 12 and 14

机译：[60]富勒烯的新三氟甲基化衍生物，C_（60）（CF_3）_n，n = 12和14

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New isomers of C_(60)(CF_3)_(12) and C_(60)(CF_3)_(14) have been isolated from mixtures obtained via reaction of C_(60) or S_6-C_(60)(CF_3)_(12) with CF-3I; they were characterized by single crystal XRD study and investigated theoretically by means of DFT calculations. Recent progress in the synthesis and isolation of trifluoromethylated fullerene derivatives led to the structural characterization of numerous C_(60)(CF_3)_n compounds in the range of n = 2-18.

机译：从通过C_（60）或S_6-C_（60）（CF_3）_反应获得的混合物中分离出C_（60）（CF_3）_（12）和C_（60）（CF_3）_（14）的新异构体（12）使用CF-3I；它们通过单晶XRD研究表征，并通过DFT计算进行理论研究。三氟甲基化富勒烯衍生物的合成和分离的最新进展导致在n = 2-18范围内的许多C_（60）（CF_3）_n化合物的结构表征。

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《Chemical Communications》 |2007年第45期|p.4794-4796|共3页
作者
Nadezhda A. Omelyanyuk; Alexey A. Goryunkov; Nadezhda B. Tamm; Stanislav M. Avdoshenko; Ilya N. Ioffe; Lev N. Sidorov; Erhard Kemnitz; Sergey I. Troyanov;
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1. New isomers of trifluoromethylated fullerene: C_(60)(CF3)_(12) and C_(60)(CF3)_(14) [J] . N.A. Samokhvalova, P. A. Khavrel, A. A. Goryunkov Russian Chemical Bulletin . 2008,第12期

机译：三氟甲基化富勒烯的新异构体：C_（60）（CF3）_（12）和C_（60）（CF3）_（14）
2. Selective Synthesis of a Trifluoromethylated Fullerene and the Crystal Structure of C_(60)(CF_3)_(12) [J] . Sergey I. Troyanov, Anton Dimitrov, Erhard Kemnitz Angewandte Chemie . 2006,第12期

机译：三氟甲基化富勒烯的选择性合成和C_（60）（CF_3）_（12）的晶体结构
3. Poly(trifluoromethyl)fullerene Radical Anions.An ESR/Vis-NIR Spectroelectrochemical Study of C_(60)F_(2,4)and C_(60)(CF_3)_(2,10) [J] . Alexey A.Popov, Jan Tarabek, Ivan E.Kareev, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第43期

机译：聚（三氟甲基）富勒烯自由基阴离子.C_（60）F_（2,4）和C_（60）（CF_3）_（2,10）的ESR / Vis-NIR光谱电化学研究
4. Trends in solubility behavior of C_(60), C_(60) and a C_(60) piperizine derivative inaromatic solvents [C] . J. J. Tian, A.L. Smith, E.B. Stukalin The Meeting of the Electrochemical Society . 2001

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5. Design, synthesis and characterization of multi-cationic [60]fullerene derivatives; Photosensitizers for antimicrobial photodynamic therapy. [D] . Thota, Sammaiah. 2012

机译：多阳离子[60]富勒烯衍生物的设计，合成和表征；用于抗菌光动力疗法的光敏剂。
6. Distribution and Biomarker of Carbon-14 Labeled Fullerene C60 (14C(U)C60) in Pregnant and Lactating Rats and their Offspring after Maternal Intravenous Exposure [O] . Rodney W. Snyder, Timothy R. Fennell, Christopher J. Wingard, -1

机译：孕期和哺乳期大鼠及其子代静脉注射碳-14标记的富勒烯C60（14C（U） C60）的分布和生物标志物
7. Structure, Dynamics, and Phase Transitions in the Fullerene Derivatives C_{60}O and C_{61}H_{2} [O] . Meingast C., Roth G., Pintschovius L., 1996

机译：富勒烯衍生物C_ {60} O和C_ {61} H_ {2}的结构，动力学和相变
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机译：富勒烯衍生物的理论和实验研究：C60H2，C60H4，C70H2和C60（CH2）2

New trifluoromethylated derivatives of [60]fullerene, C_(60)(CF_3)_n with n = 12 and 14

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