Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: I. from isolated cluster to 1-D chain

摘要

The hydrothermal reactions of [A-α-SiW_9O_(34)]~(10-) /[A-α-PW_9O_(34)]~(9-) with NiCl_2·6H_2O and amines yielded four unprecedented hybrid high-nuclear Ni-subsituted polyoxotungstates.