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SURFACE OXIDIZED CARBON FIBERS: Ⅱ. CHEMICAL MODIFICATION

机译:表面氧化碳纤维:Ⅱ。化学修饰

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The surface functional groups of various surface oxidized carbon fibers were chemically modified by reaction with methanol/HCl and reduction with sodium boron hydride and lithium aluminum hydride. Investigations of these fibers before and after chemical modification by CAM (contact angle measurements), XPS and TPD showed that none of the reactions are selective as expected. Complete conversion of the relevant groups at the fiber surface cannot be determined with the methods available. Therefore, they have to be handled very carefully especially if used for studying adhesion of polymers.
机译:各种表面氧化碳纤维的表面官能团通过与甲醇/ HCl反应进行化学改性,然后用氢化硼钠和氢化锂铝进行还原。对这些纤维在通过CAM(接触角测量),XPS和TPD进行化学修饰之前和之后的研究表明,这些反应均未达到预期的选择性。可用表面方法无法确定纤维表面上相关基团的完全转化。因此,必须非常小心地处理它们,特别是如果用于研究聚合物的粘合性。

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