Measurement of methane emissions from abandoned oil and gas wells in Hillman State Park, Pennsylvania

摘要

Abandoned oil and gas wells, improperly plugged or unplugged, present a risk to current and future oil and gas development because they provide a potential pathway for unwanted gas and fluid migration to the surface. The appropriate emission factor for gaseous emissions from these wells is uncertain, as a limited number of studies have reported abandoned wells as a methane emissions source. A helicopter-based survey that mapped methane concentration and located wells by detecting magnetic anomalies was conducted in Hillman State Park in southwestern Pennsylvania. Although well finding via aerial survey was successful, elevated methane concentrations due to emissions from wells in the survey area were not detected by helicopter as abandoned wells were likely too small a source of methane to detect from elevations that helicopters fly at (tens of meters). Measurement of methane emission rates from 31 wells were collected using several techniques that are compared and evaluated for their effectiveness: Hi Flow sampler, field-portable flame ionization detector, infrared camera, dynamic flux chamber and bag sampling. Nine of the 31 wells were buried; average methane flux for these wells was not statistically different from the background. Mass flow rate from the remaining 22 wells ranged from non-detection (less than 0.09kg CH4/day) to 4.18kg CH4/day with a mean of 0.70 kg/well/day (median of 0.24kg CH4/day/well) and a sample standard of error of 0.21kg CH4/well/day. This emission factor, while not intended for exclusive use in developing a methane emissions inventory for abandoned oil and gas wells, contributes to the growing amount of methane emissions data for this source category. The results from the aerial survey, ground-based well location verification and emissions measurements, and the evaluation of measurement approaches described here, provide a comprehensive characterization of abandoned wells in one field that can inform future measurement studies.