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Preparation and Characterization of Polyaniline/Hexagonal Boron Nitride Composites

机译:聚苯胺/六方氮化硼复合材料的制备与表征

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摘要

Polyaniline (PANI) is one of the most studied conductive polymer with several unique properties and good conductivity. In this study it was aimed to prepare Polyaniline (PANI)/Hexagonal boron nitride (h-BN) composites. Chemical structures of the composites were characterized by FTIR analysis. Thermal properties of these novel composites were analyzed by TGA and DSC measurements. Glass transition temperatures and char yields of the composites increased with increasing h-BN percentage. FTIR, XRD and UV measurements indicated that the boron atoms in h-BN particles interact with the unpaired electrons in nitrogen atoms of PANI. Dielectric measurements revealed dipolar polarization behavior of the composites.
机译:聚苯胺(PANI)是研究最多的导电聚合物之一,具有多种独特的性能和良好的导电性。在这项研究中,目的是制备聚苯胺(PANI)/六方氮化硼(h-BN)复合材料。通过FTIR分析表征复合材料的化学结构。通过TGA和DSC测量分析了这些新型复合材料的热性能。复合材料的玻璃化转变温度和炭产率随h-BN百分比的增加而增加。 FTIR,XRD和UV测量表明,h-BN颗粒中的硼原子与PANI氮原子中的不成对电子相互作用。介电测量表明复合材料的偶极极化行为。

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