Effect of Ce_2O_3 and CaO/Al_2O_3 on the Phase, Melting Temperature and Viscosity of CaO-Al_2O_3-10 Mass% SiO_2 Based Slags

摘要

The melting temperature and viscosity of CaO-Al_2O_3-10 mass% SiO_2 based slag system with various concentrations of Ce_2O_3 have been studied using the melting point detector and the rotating crucible viscometer. And X-ray diffraction analysis has been used for phase identification. The results show that cerium is stable in Ce~(3+) state existing mainly as CeAlO_3 and Ce_(4.67)(SiO_4)_3O phase in slags and CeAlO_3 phase appears in green color. The melting temperature gently decreases with Ce_2O_3 additions in 1.57 of CaO/Al_2O_3. Moreover, the melting temperature increases first and then decreases with the increasing of CaO/Al_2O_3 from 1.17 to 1.52 at 4.47 mass% Ce_2O_3. In addition, at 1.57 of CaO/Al_2O_3, the viscosity increases at the beginning and then decreases with the increasing Ce_2O_3 content from 4.39 to 11.48 mass%. Furthermore, at 4.47 mass% Ce_2O_3, the viscosity decreases at the first and then increases with the increasing CaO/Al_2O_3 from 1.17 to 1.52. Meanwhile, from the slopes of the Arrhenius relationship for viscosity, the activation energy range of viscous flow is from 179.07 to 433.70 kJ/mol. On the basis of these results, slag composition of 45.64 mass% CaO-39.02 mass% Al_2O_3-1O.73 mass% SiO_2-3.83 mass% Ce_2O_3 is melting temperature of 1361 ℃ and viscosity of 0.398 Pa-s (1500 ℃), which has superiority and is more suitable for the actual refining process.