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Experimentally determined Henry's Law coefficients of phenol, 2-methylphenol and 2-nitrophenol in the temperature range 281-302 K

机译:在281-302 K的温度范围内实验确定的苯酚,2-甲基苯酚和2-硝基苯酚的亨利定律系数

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摘要

The Henry's Law coefficient is a key physical parameter in the partitioning, and hence environmental fate, of a chemical species between air and water. Despite the acknowledged polluting potential of phenol, 2-methylphenol (o- cresol) and 2-nitrophenol, there is extremely poor agreement in the literature of their Henry's law coefficients and, in particular, no apparent systematic measurement of the variation with temperature. Here, a temperature-controlled column-stripping method was employed to determine Henry's Law coefficients for these compounds over the temperature range 281-302 K.
机译:亨利定律系数是化学物质在空气和水之间的分配以及因此决定环境命运的关键物理参数。尽管公认的苯酚,2-甲基苯酚(邻甲酚)和2-硝基苯酚具有潜在的污染潜力,但文献中关于它们的亨利定律系数的一致性极差,尤其是没有明显的系统测量随温度变化的方法。在此,采用温度控制的柱汽提方法确定这些化合物在281-302 K的温度范围内的亨利定律系数。

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