Real-world emissions of carbonyls from vehicles in an urban tunnel in south China

摘要

Carbonyls play a vital role in atmospheric photochemistry. Vehicle emission is among most important primary emission sources of carbonyls in urban areas, yet knowledge is quite scarce about real-world emissions of carbonyls with the changing on-road vehicle fleets. In this study, emissions of carbonyls were characterized based on tests in a busy urban tunnel in south China. Emission factor (EF) of carbonyls was measured to be 9.89 +/- 0.65 mg km(-1) on average, in which formaldehyde alone shared 53.1% with an EF of 5.25 +/- 0.35 mg km(-1), followed by acetaldehyde with an EF of 1.47 +/- 0.13 mg km(-1). Glyoxal and methylglyoxal showed identical EFs of 0.18 +/- 0.02 mg km(-1). Multiple linear regression retrieved total carbonyl EFs of 5.68, 47.71 and 35.09 mg km(-1) and ozone formation potentials (OFPs) of 38.4, 329.3, and 242.4 mg km(-1) for gasoline, diesel and liquefiedpetroleum gas vehicles (LPGVs), respectively. The unexpectedly high carbonyl emissions from LPGVs were largely attributed to the lack of after-treatment systems or the inefficiency of the after-treatment systems. Among vehicle-emitted non-methane hydrocarbons and carbonyls, carbonyls could contribute similar to 20% of the total OFPs while they only accounted for 7.1% of the total mass.