Pollution level and inhalation exposure of ambient aerosol fluoride as affected by polymetallic rare earth mining and smelting in Baotou, north China

摘要

Airborne fluoride associated with total suspended particles (TSP) and respirable particulate (PM10) in the rare earth mining and smelting areas were analyzed during August 2012 and March 2013. In March, average concentrations of fluoride bound to TSP in the mining and smelting areas were 0.598 +/- 0.626 mu g/ m(3) and 3.615 +/- 4.267 g/m(3), respectively, whereas that in August were 0.699 +/- 0.801 g/m(3) and 1.917 +/- 2.233 g/m(3), respectively. TSP samples were classified into four categories by different sampling periods and locations using Kohonen's self-organizing map, which demonstrates that high airborne fluoride concentrations in March in the smelting area were probably attributed to industrial emissions from smelting activities and wind-blown dust from tailings pond, influenced by meteorologic parameters such as temperature, relative humidity, precipitation and wind speed. The mean daily amount of fluoride inhaled in the mining and smelting areas were estimated to be in the range of 2.77-57.61 mu g/day and 339-6432 mu g/day, respectively. These results indicate the high potential exposure level of fluoride inhaled for local residents in the polymetallic mining and smelting areas. (C) 2017 Elsevier Ltd. All rights reserved.