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The Effects of Pore Fluids with Different Dielectric Constants on the Geotechnical Behaviour of Kaolinite

机译:不同介电常数的孔隙流体对高岭石岩土行为的影响

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The properties of pore fluid in clayey soil are usually influential on the intergranular physicochem-ical forces, i.e., on the geotechnical properties of clay. In this paper, the Atterberg limits of kaolinite were determined for pure water and four different chemical fluids with various concentrations (20,40,60 and 80 %) whose dielectric constants represent a wide range of interval, and kaolinite's shear strength and compression behaviors were investigated by using the specimens obtained by consolidating the mixtures under 100 kPa pressure with water content twice their liquid limits. During the tests, an optical microscope was used to take the photographic views of the structural changes taking place on kaolinite due to the changing pore fluids. According to the experimental results, the effect of the chemical fluids caused to have increase in shear strength values and decrease in compression and swelling index values obtained by the consolidation tests. Moreover, kaolinite's liquid limit increased with the increasing chemical fluid concentration and decreasing dielectric constant of the pore fluid. The changes observed on the geotechnical properties of kaolinite subjected to chemical fluids can be explained with intergranular Van der Waals attraction forces whose increase causes the flocculation of particles and the tendency of the clayey soil to behave like the silt-fine sand. Additionally, the optical microscope views taken during the experiments also supported these conditions clearly.
机译:黏土中孔隙流体的性质通常会影响粒间的物理化学力,即黏土的岩土力学性质。本文确定了纯水和四种不同浓度(20%,40%,60%和80%)的化学流体的高岭石的阿特伯格极限,它们的介电常数代表大范围的区间,高岭石的剪切强度和压缩行为为通过使用在100 kPa压力下将混合物固结,水含量是其液体极限值两倍的固结物获得的试样进行研究。在测试过程中,使用光学显微镜拍摄了由于孔隙流体变化而在高岭石上发生的结构变化的照片。根据实验结果,通过固结测试获得的化学流体的作用使剪切强度值增加而压缩和溶胀指数值减小。此外,高岭石的液体极限随着化学流体浓度的增加和孔隙流体的介电常数的降低而增加。高岭石在化学流体作用下所观察到的岩土特性的变化可以用粒间范德华吸引力来解释,其增加会引起颗粒的絮凝,并使粘土质的行为像粉砂细沙。另外,实验过程中获得的光学显微镜也清楚地支持了这些条件。

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