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Hydrothermal deposition of CoS nanostructures and its multifunctional applications in supercapattery and water electrolyzer

机译:CoS纳米结构的水热沉积及其在超级电容器和水电解槽中的多功能应用

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摘要

The development of sustainable energy conversion and storage systems is on demand to ease the energy needs and restrict environmental pollution. Here, we account a unique multifunctional flake-like CoS deposited over the flexible carbon cloth (CoS@CC) by a facile hydrothermal technique. The single-phase hexagonal structured CoS@CC with high crystallinity was identified through the XRD analysis. The morphological feature portrays the uniform distribution of flake-like CoS over carbon cloth. The electrocatalytic properties of the prepared flake-like CoS (CoS@CC) suggests improved electroactivity of requiring minimal overpotentials of 280 mV (OER) and 264 mV (HER) to accomplish a pre-eminent current density of 20 mA cm(-2). In addition, a lab-scale water splitting system was projected to achieve a current density of 10 mA cm(-2) with a low cell voltage of 1.65 V. In view to driving the fabricated water splitting system, a flexible (CoS@CC parallel to rGO) supercapattery was fabricated to deliver an improved specific energy of 38 Wh kg(-1) at a superior specific power of 533 W kg(-1). Therefore, the prepared CoS@CC electrode with improved flexibility, useful catalytic activity, expressive kinetics, and resilient strength serves as a multifunctional material for prospective energy conversion and storage systems.
机译:迫切需要开发可持续的能源转换和存储系统,以缓解能源需求并限制环境污染。在这里,我们介绍了一种通过简便的水热技术沉积在柔性碳布(CoS @ CC)上的独特的多功能片状CoS。通过XRD分析鉴定出具有高结晶度的单相六方结构的CoS @ CC。形态特征描绘了片状CoS在碳布上的均匀分布。制备的片状CoS(CoS @ CC)的电催化性能表明电活性得到改善,需要最小的280 mV(OER)和264 mV(HER)的过电势才能实现20 mA cm(-2)的卓越电流密度。此外,预计实验室规模的水分解系统可实现10 mA cm(-2)的电流密度,且电池电压低至1.65V。为驱动人造水分解系统,灵活的(CoS @ CC与rGO平行)制造了超级电池,以在533 W kg(-1)的较高比功率下提供了38 Wh kg(-1)的改进比能。因此,所制备的具有改善的柔韧性,有用的催化活性,表达动力学和回弹强度的CoS @ CC电极可作为用于预期能量转换和存储系统的多功能材料。

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