Synthesis of graphitized carbon, nanodiamond and graphene supported Li4Ti5O12 and comparison of their electrochemical performance as anodes for lithium ion batteries

摘要

Graphitized carbon (GC), nanodiamond (ND) and graphene (GE) supported Li4Ti5O12 (LTO) composites have been synthesized via a solid-state reaction, respectively. The particle sizes of LTO/GC, LTO/ND and LTO/GE are smaller than pure LTO. When tested as the anode for lithium ion batteries, the discharge capacities of LTO, LTO/GC, LTO/ND and LTO/GE composites are 100.1 mAh g(-1), 150.4 mAh g(-1), 90.4 mAh g(-1) and 218.3 mAh g(-1) at the current density of 175 mA g(-1) after 500 cycles. Their rate capacities retain 59.8%, 80.0%, 81.0% and 85.7% at the current density of 175 mA g(-1), 438 mA g(-1), 875 mA g(-1) and 175 mA g(-1), respectively. Moreover, the recovery rates of their rate capacities are 78.6%, 83.4%, 88.9% and 90.1% when returned to the current density of 175 mA g(-1), respectively. The reasons can be attributed to the synergistic effect between GC (ND and GE) and LTO as well as the features of the different carbon supports. This strategy, with the carbon constituting a good supporting structure, is an effective way to improve the cycling performance of anode materials for lithium ion batteries. (C) 2016 Elsevier B.V. All rights reserved.