Fabrication of porous carbon sphere@SnO2@carbon layer coating composite as high performance anode for sodium-ion batteries

摘要

SnO2 has triggered lots of research efforts as anode for sodium-ion batteries. However, the volume expansion and poor conductivity lead to an unsatisfactory electrochemical performance for the practical application of SnO2. In this work, a novel carbon-coated SnO2 supported by porous carbon sphere composite is synthesized by hydrothermal process combining with annealing method. The porous carbon sphere@SnO2@carbon layer coating composite anode delivers a reversible capacity of 326 mAh g(-1) over 80 cycles at a current density of 50 mA g(-1). Even at 1600 mA g(-1), a capacity of 82 mAh g(-1) is still maintained after 550 cycles. Such excellent performance can be ascribed to the unique structure, which efficiently accommodates volume expansion, enhances conductivity and offers shortened sodium-ion transport pathway. The charge-storage mechanisms can be comprised of diffusion-controlled reaction and pseudocapacitance effect. At high scan rate of 1.0 mV s(-1), the capacity contribution of pseudocapacitance effect could reach as high as 78%. (C) 2017 Elsevier B.V. All rights reserved.