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Okra (Hibiscus esculentus) seed oil for biodiesel production

机译:黄秋葵(Hibiscus esculentus)种子油用于生物柴油生产

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摘要

Biodiesel was derived from okra (Hibiscus esculentus) seed oil by methanol-induced transesterification using an alkali catalyst. Transesterification of the tested okra seed oil under optimum conditions: 7:1 methanol to oil molar ratio, 1.00% (w/w) NaOCH_3 catalyst, temperature 65 ℃ and 600 rpm agitation intensity exhibited 96.8% of okra oil methyl esters (OOMEs) yield. The OOMEs/biodiesel produced was analyzed by GC/MS, which showed that it mainly consisted of four fatty acids: linoleic (30.31%), palmitic (30.23%), oleic (29.09%) and stearic (4.93%). A small amount of 2-octyl cyclopropaneoctanoic acid with contribution 1.92% was also established. Fuel properties of OOMEs such as density, kinematic viscosity, cetane number, oxidative stability, lubricity, flash point, cold flow properties, sulfur contents and acid value were comparable with those of ASTM D 6751 and EN 14214, where applicable. It was concluded that okra seed oil is an acceptable feedstock for biodiesel production.
机译:生物柴油由秋葵(Hibiscus esculentus)种子油通过甲醇诱导的酯交换反应(使用碱性催化剂)制得。在最佳条件下,经测试的秋葵籽油的酯交换反应:甲醇与油的摩尔比为1:1,1.00%(w / w)NaOCH_3催化剂,温度为65℃,搅拌强度为600 rpm,显示出96.8%的秋葵油甲酯(OOMEs)产率。通过GC / MS分析生产的OOMEs /生物柴油,结果表明它主要由四种脂肪酸组成:亚油酸(30.31%),棕榈酸(30.23%),油酸(29.09%)和硬脂酸(4.93%)。还建立了少量的贡献率为1.92%的2-辛基环丙烷辛酸。如果适用,OOMEs的燃料特性,例如密度,运动粘度,十六烷值,氧化稳定性,润滑性,闪点,冷流特性,硫含量和酸值,与ASTM D 6751和EN 14214相当。结论是,秋葵籽油是生物柴油生产可接受的原料。

著录项

  • 来源
    《Applied Energy》 |2010年第3期|779-785|共7页
  • 作者单位

    Department of Chemistry and Biochemistry, University of Agriculture. Faisalabad 38040. Pakistan;

    Department of Chemistry and Biochemistry, University of Agriculture. Faisalabad 38040. Pakistan Department of Industrial Chemistry, Government College University, Faisalabad 38000, Pakistan;

    Department of Botany, University of Agriculture, Faisalabad 38040, Pakistan;

    Department of Chemistry and Biochemistry, University of Agriculture. Faisalabad 38040. Pakistan;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    okra seeds; oil extraction; transesterification; biodiesel; gas chromatography/mass spectrometry; fuel properties;

    机译:秋葵种子;采油;酯交换生物柴油气相色谱/质谱法;燃料性质;
  • 入库时间 2022-08-18 00:10:20

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