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Progress in Nanoengineered Microstructures for Tunable High-Current, High-Temperature Superconducting Wires

机译:可调谐大电流,高温超导线材的纳米工程微结构研究进展

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High critical current densities (J_c) in thick films of the Y_1Ba_2Cu_3O_(7-δ) (YBCO, T_≈ 92 K) superconductor directly depend upon the types of nanoscale defects and their densities within the films. A major challenge for developing a viable wire technol ogy is to introduce nanoscale defect structures into the YBCO grains of the thick film suitable for flux pinning and the tailoring of the superconducting properties to specific, application-dependent, temperature and magnetic field conditions. Concurrently, the YBCO film needs to be integrated into a macroscopically defect-free conductor in which the grain-to-grain connectivity maintains levels of inter-grain J_c that are comparable to the intra-grain J_c. That is, high critical current (I_c) YBCO coated conductors must contain engineered inhomo-geneities on the nanoscale, while being homogeneous on the macroscale. An analysis is presented of the advances in high-performance YBCO coated-conductors using chemical solution deposition (CSD) based on metal trifluoroa-cetates and the subsequent processing to nano-engineer the microstructure for tuneable superconducting wires. Multi-scale structural, chemical, and electrical investigations of the CSD film processes, thick film development, key microstructural features, and wire properties are presented. Prospects for further development of much higher I_c wires for large-scale, commercial application are discussed within the context of these recent advances.
机译:Y_1Ba_2Cu_3O_(7-δ)(YBCO,T_≈92 K)超导体的厚膜中的高临界电流密度(J_c)直接取决于纳米级缺陷的类型及其在膜中的密度。开发可行的导线技术的主要挑战是将纳米级缺陷结构引入厚膜的YBCO晶粒中,以适合磁通钉扎以及根据特定的,与应用相关的温度和磁场条件调整超导性能。同时,需要将YBCO薄膜集成到宏观上无缺陷的导体中,在该导体中,晶粒与晶粒之间的连通性可维持与晶粒内J_c相当的晶粒间J_c水平。也就是说,高临界电流(I_c)YBCO涂层的导体必须在纳米级上包含工程异质性,而在宏观上是均质的。提出了使用基于金属三氟乙酸根的化学溶液沉积(CSD)的高性能YBCO涂层导体的进展以及随后的工艺,以对可调谐超导线进行微结构纳米加工的分析方法。介绍了CSD膜工艺,厚膜显影,关键的微结构特征和导线特性的多尺度结构,化学和电学研究。在这些最新进展的背景下,讨论了用于大规模商业应用的更高I_c线的进一步开发的前景。

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