MEASUREMENTS AND MODEL SIMULATIONS OF SURFACE OZONE VARIATIONS AT DIFFERENT BACKGROUND CONCENTRATIONS OF THE PRECURSORS

摘要

Ozone photochemical production and loss in very different environments at Waliguan baseline station and Lin'an background station were simulated by using the measurement data and photochemical box model. The results show that net ozone photochemical production rate is negative, about 0. 5 ppb/d, at Waliguan baseline sation, because of very low precursor concentrations. But at Lin'an background station, the net photochemical ozone production is positive, about 2-3 ppb/ h, which is very closed with the measurement at Lin'an. That means ozone production was controlled by photochemical reactions at Lin'an background station, because of the higher precursor concentrations. The net destruction rate, at Waliguan Mt., is not large, so that future increase in anthropogenic emission of reactive nitrogen will lead to larger production rates of steady-state O_3 concentration.