The determination of adsorbable organically bound halogens (AOX) in soil: interlaboratory comparisons and reference materials

摘要

The interlaboratory variability in the quantification of adsorbable organically bound halogens (AOX) in industrially contaminated soil is presented. Three consecutive rounds of a proficiency testing scheme, in which between 88 and 119 routine laboratories participated, yielded relative reproducibility standard deviations between 7 and 20% at AOX contents between 10.9 and 268 mg kg−1. Nineteen laboratories with established proficiency were invited to participate in the certification of the AOX content in three soil reference materials meant for the internal quality control in analytical laboratories. The certified values are (1349 ± 59) mg kg−1, (80 ± 7) mg kg−1 and (102 ± 8) mg kg−1, respectively.