Isotope clusters in library electron ionization mass spectra of germanes often appear a few u lower than theoretically expected from elemental composition; for example, the dominant peak of the Ge4H10+ pattern is shifted 8 u down. This phenomenon is due to combinations of three essential components: the molecular ion GenH2n+2+ and two products of hydrogen elimination, GenH+ and Gen+. Using these components, isotope clusters can be accurately projected for germanium hydrides from Ge2H6 up to Ge5H12.
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