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Chloride Diffusion Property of Hybrid Basalt–Polypropylene Fibre-Reinforced Concrete in a Chloride–Sulphate Composite Environment under Drying–Wetting Cycles

机译:干湿循环下氯化物硫酸盐复合环境中杂交玄武岩 - 聚丙烯纤维增强混凝土的氯化物扩散特性

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摘要

The effect of fibre reinforcement on the chloride diffusion property of concrete is controversial, and the coupling effect of sulphate erosion and drying–wetting cycles in marine environments has been neglected in previous studies. In this study, the chloride diffusion property of hybrid basalt–polypropylene fibre-reinforced concrete subjected to a combined chloride–sulphate solution under drying–wetting cycles was investigated. The effects of basalt fibre (BF), polypropylene fibre (PF), and hybrid BP–PF on the chloride diffusion property were analysed. The results indicate that the presence of sulphate inhibits the diffusion of chloride at the early stage of erosion. However, at the late stage of erosion, sulphate does not only accelerate the diffusion of chloride by causing cracking of the concrete matrix but also leads to a decrease in the alkalinity of the pore solution, which further increases the risk of corrosion of the reinforcing steel. An appropriate amount of fibre can improve the chloride attack resistance of concrete at the early stage. With the increase in erosion time, the fibre effectively prevents the formation and development of sulphate erosion microcracks, thus reducing the adverse effects of sulphate on the resistance of concrete to chloride attack. The effects of sulphate and fibre on the chloride diffusion property were also elucidated in terms of changes in corrosion products, theoretical porosity, and the fibre-matrix interface transition zone.
机译:纤维增强对混凝土氯化物扩散特性的影响是有争议的,并且在先前的研究中忽略了海洋环境中硫酸盐腐蚀和干燥润湿循环的偶联效应。在该研究中,研究了在干燥润湿循环中进行的杂合玄武岩 - 聚丙烯纤维增强混凝土的杂种玄武岩 - 聚丙烯纤维增强混凝土的氯化物扩散性能。分析了玄武岩纤维(BF),聚丙烯纤维(PF)和杂化BP-PF对氯化物扩散性的影响。结果表明,硫酸盐的存在抑制了侵蚀早期氯化物的扩散。然而,在侵蚀的晚期,硫酸盐通过引起混凝土基质的破裂而不仅加速氯化物的扩散,而且还导致孔隙溶液的碱度降低,这进一步提高了加强钢腐蚀的风险。适量的纤维可以在早期阶段改善混凝土的氯化物侵蚀性。随着侵蚀时间的增加,纤维有效地防止了硫酸盐腐蚀微裂纹的形成和发展,从而降低了硫酸盐对混凝土抗性的不利影响。在腐蚀产物,理论孔隙率和纤维 - 基质界面过渡区的变化方面还阐明了硫酸盐和纤维对氯化物扩散性的影响。

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