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Nanocomposite Fiber Based on Natural Material for Water Disinfection under Visible Light Irradiation

机译:基于天然材料的纳米复合纤维在可见光辐射下的杀菌作用

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摘要

In the last decade, pathogenic bacteria and organic micropollutants have become a major issue in the water purification process. Heterogeneous photocatalysis is a low-cost and an ecofriendly process, which provides a sustainable solution for water treatment and its utilization in rural areas. In this context, we studied the generation and the surface engineering of polyacrylonitrile (PAN)/goethite composite nanofibers for photocatalytic water remediation under visible-light illumination. The photocatalytic activity was evaluated for dye (methylene blue) degradation and bacteria inactivation, as contaminant models, of the composite nanofibers. The PAN/goethite nanofibers were elaborated by an electrospinning technique, and the morphology and the composition, before and after spin coating, were investigated by Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray (EDX). The results showed partially intercalated structures of the PAN/goethite Composite-nano-fiber (CNF) were identified by SEM and EDX analysis. The composite nanofibers exhibited high photoefficiency upon dye bleaching (only 10% left after 5 h of illumination) and bacterial deactivation and (4.4- and 3.5-fold, respectively, in less than 5 h). The steadiness and pliancy of the generated nanofibers provide a promising application in the continuous flow system.
机译:在过去的十年中,致病细菌和有机微污染物已成为水净化过程中的主要问题。异构光催化是一种低成本且生态友好的过程,它为水处理及其在农村地区的利用提供了可持续的解决方案。在这种情况下,我们研究了在可见光照射下用于光催化水修复的聚丙烯腈/针铁矿复合纳米纤维的产生和表面工程。评价了复合纳米纤维作为染料模型的染料(亚甲基蓝)降解和细菌灭活的光催化活性。 PAN /针铁矿纳米纤维通过静电纺丝技术进行了细化,并通过扫描电子显微镜(SEM)和能量色散X射线(EDX)研究了旋涂前后的形貌和组成。结果表明,通过SEM和EDX分析鉴定了PAN /针铁矿复合纳米纤维(CNF)的部分插入结构。复合纳米纤维在染料漂白(照射5小时后仅剩10%)和细菌失活后(分别在不到5小时内分别为4.4倍和3.5倍)显示出高光效率。产生的纳米纤维的稳定性和柔韧性在连续流动系统中提供了有希望的应用。

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