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A New Method for the Measurement of the Diffusion Coefficient of Adsorbed Vapors in Thin Zeolite Films Based on Magnetoelastic Sensors

机译:基于磁弹性传感器的薄沸石膜吸附蒸气扩散系数测量新方法

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摘要

In the current work an experimental method is used in order to calculate the diffusivity (diffusion coefficient) of various vapors in thin zeolite films. The method is based on adsorption data from magnetoelastic sensors on top of which a zeolite layer was synthesized, and the diffusivity is extracted by fitting the data to Fick’s laws of diffusion. In particular, the method is demonstrated for two volatile organic compound (VOC) vapors on two different zeolites, the p-Xylene adsorption in Faujasite type zeolite with at and the propene adsorption in Linde Type A type zeolite with at , two diffusion coefficients which are extracted experimentally for first time. Our results are within the order of magnitude of other VOC/zeolite values reported in literature.
机译:在当前的工作中,使用一种实验方法来计算沸石薄膜中各种蒸气的扩散率(扩散系数)。该方法基于磁弹性传感器的吸附数据,在其上面合成了沸石层,并通过使数据符合Fick扩散定律来提取扩散率。特别是,该方法针对两种挥发性沸石上的两种挥发性有机化合物(VOC)蒸气进行了论证,其中对甲苯在Faujasite型沸石中的对二甲苯吸附和在Linde A型沸石中对PT的丙烯吸附,两个扩散系数分别为。首次通过实验提取。我们的结果与文献报道的其他VOC /沸石值处于数量级内。

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