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Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis

机译:编织不锈钢网作为碱性水分解电解的气体分离膜

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摘要

A 316-grade woven stainless-steel mesh membrane was investigated as a gas-separation membrane for alkaline water-splitting electrolysis. Its resistance was measured using electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV), with the conclusion that it presented approximately half the resistance of a comparable commercial alternative (Zirfon ). Its gas-separation performance was analysed using gas chromatography (GC) at 140 mA cm , where it achieved 99.25% purity at the hydrogen outlet of the electrolyser. This fell to 97.5% under pumped circulation, which highlights that it is sensitive to pressure differentials. Nevertheless, this mixture is still more than a factor two inside the upper flammability limit of hydrogen in oxygen. It is hoped that such a low-cost material may bring entry-level electrolysis to many hitherto discounted applications.
机译:研究了一种316级不锈钢编织网状膜作为用于碱性水分解电解的气体分离膜。使用电化学阻抗谱(EIS)和线性扫描伏安法(LSV)测量了它的电阻,得出的结论是,它的电阻约为可比较的商用替代品(Zirfon)的一半。使用气相色谱仪(GC)在140 mA cm处分析了其气体分离性能,在电解池的氢气出口处达到了99.25%的纯度。在泵送循环下下降到97.5%,这表明它对压差敏感。但是,这种混合物在氧气中氢的易燃性上限内仍超过两倍。希望这种低成本的材料可以将入门级电解带入许多迄今打折的应用中。

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