Iron(II) Spin Crossover Complexes with 44′-Dipyridylethyne—Crystal Structures and Spin Crossover with Hysteresis

摘要

Three new iron(II) 1D coordination polymers with cooperative spin crossover behavior showing thermal hysteresis loops were synthesized using N O Schiff base-like equatorial ligands and 4,4′-dipyridylethyne as a bridging, rigid axial linker. One of those iron(II) 1D coordination polymers showed a 73 K wide hysteresis below room temperature, which, upon solvent loss, decreased to a still remarkable 30 K wide hysteresis. Single crystal X-ray structures of two iron(II) coordination polymers and -dependent powder XRD patterns are discussed to obtain insight into the structure property relationship of those materials.