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Progress and Perspectives on Ceramic Membranes for Solvent Recovery

机译:溶剂回收用陶瓷膜的研究进展与展望

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摘要

With the increase in demand for commodities in the world, it is advisable to conserve resources. In the case of liquid wastes generated from pharmaceutical and petroleum industries, an unconventional solution is provided for the regeneration of solvents. However, this solvent recovery can be carried out using various efficient methods. Recently, Mixed Matrix Membranes (MMM) obtained by the addition of nanoparticles into a polymer matrix as reinforcements, or using a material with a well-defined inorganic network as a membrane like zeolite, silica based, Zeolite imidazolate frameworks (ZIFs) and Metal organic frameworks (MOFs), were explored for a solvent recovery process. These membranes possess characteristics such as high selectivity, flux and stability at various environmental conditions for the solvent recovery process. In this review, we have covered the polymer, nanocomposites, and ceramic membranes for solvent recovery through the pervaporation and organic solvent nanofiltration processes. The key challenges faced by the materials such as MOFs, zeolite, silica, zeolite and ZIFs when they are fabricated (through in situ synthesis or secondary growth process) as membranes and separation of solvents to explore for the solvent recovery process are reviewed.
机译:随着世界对商品需求的增加,建议节约资源。对于从制药和石油工业产生的液体废物,提供了一种用于溶剂再生的非常规解决方案。然而,可以使用各种有效方法来进行该溶剂回收。最近,通过将纳米颗粒添加到聚合物基质中作为增强材料,或使用具有良好定义的无机网络的材料作为膜(如沸石,二氧化硅基,咪唑沸石骨架(ZIFs)和金属有机物)获得的混合基质膜(MMM)探索了用于溶剂回收过程的构架(MOF)。这些膜在溶剂回收过程的各种环境条件下都具有诸如高选择性,通量和稳定性等特性。在这篇综述中,我们涵盖了用于通过全蒸发和有机溶剂纳米过滤工艺回收溶剂的聚合物,纳米复合材料和陶瓷膜。审查了诸如MOF,沸石,二氧化硅,沸石和ZIFs等材料在制造时(通过原位合成或二次生长过程)作为膜和溶剂分离方法以探索溶剂回收过程所面临的主要挑战。

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