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Modification Effects of Carbon Nanotube Dispersion on the Mechanical Properties Pore Structure and Microstructure of Cement Mortar

机译:碳纳米管分散体对水泥砂浆力学性能孔结构和微观结构的改性作用

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摘要

Carbon nanotubes (CNTs) are very effective in improving the performance of cement-based materials. Mechanical properties and pore structure were investigated for cement mortar with CNTs. Meanwhile, the composite morphology of CNT–cement material and the evolution of hydration products were observed by scanning electron microscope (SEM), and the quantitative relationship between mechanical properties and pore structure was analyzed. The results indicated that the strength of mortar increased with the addition of 0.05% CNTs and decreased when the fraction of CNTs increased to 0.5%. The porosity of mortar with dispersed CNTs increased significantly, as these pores may be introduced by the dispersant. The quantitative relationship between porosity and strength proved that the increased porosity is the reason for the decreased strength of mortar with 0.5% CNT content, while mortar matrix strength with 0.05% and 0.5% CNTs increased by 44.03% and 71.18%, respectively. SEM images show that CNTs are dispersed uniformly in the mortar without obvious agglomeration and that the CNTs and hydration products form a meshwork structure, which is the mechanism by which CNTs can enhance the strength of the cement matrix.
机译:碳纳米管(CNT)在改善水泥基材料的性能方面非常有效。研究了碳纳米管水泥砂浆的力学性能和孔结构。同时,用扫描电镜观察了碳纳米管水泥材料的复合形态和水合产物的演变,分析了力学性能与孔结构的定量关系。结果表明,砂浆的强度随着添加0.05%CNT的增加而增加,而当CNTs的比例增加到0.5%时降低。分散有CNT的砂浆的孔隙率显着增加,因为这些孔可能由分散剂引入。孔隙率与强度之间的定量关系证明,孔隙率增加是CNT含量为0.5%的砂浆强度降低的原因,而CNTs为0.05%和0.5%的砂浆基质强度分别提高了44.03%和71.18%。 SEM图像表明,CNTs均匀地分散在砂浆中,没有明显的团聚,并且CNTs和水合产物形成网状结构,这是CNTs增强水泥基体强度的机理。

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