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Novel Poly(Methyl Methacrylate) Containing Nanodiamond to Improve the Mechanical Properties and Fungal Resistance

机译:新型的含有纳米金刚石的聚甲基丙烯酸甲酯可改善机械性能和抗真菌性

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摘要

Herein we evaluate the effect of nanodiamond (ND) incorporation on the mechanical properties of poly(methyl methacrylate) (PMMA) nanocomposite. Three quantities of ND (0.1, 0.3, and 0.5 wt.%) were tested against the control and zirconium oxide nanoparticles (ZrO). Flexural strength and elastic modulus were measured using a three-point bending test, surface hardness was evaluated using the Vickers hardness test, and surface roughness was evaluated using atomic force microscopy (AFM), while fungal adhesion and viability were studied using . Samples were also analyzed for biofilm thickness and biomass in a saliva-derived biofilm model. All groups of ND-PMMA nanocomposites had significantly greater mean flexural strengths and statistically improved elastic modulus, compared to the control and ZrO groups ( < 0.001). The Vickers hardness values significantly increased compared to the control group ( < 0.001) with 0.3% and 0.5% ND. ND addition also gave significant reduction in fungal adhesion and viability ( < 0.001) compared to the control group. Finally, salivary biofilm formation was markedly reduced compared to the ZrO group. Hence, the incorporation of 0.1–0.5 wt.% ND with auto- polymerized PMMA resin significantly improved the flexural strength, elastic modulus, and surface hardness, and provided considerable fungal resistance.
机译:本文中,我们评估了掺入纳米金刚石(ND)对聚甲基丙烯酸甲酯(PMMA)纳米复合材料的机械性能的影响。针对对照和氧化锆纳米颗粒(ZrO)测试了三种量的ND(0.1、0.3和0.5重量%)。使用三点弯曲测试测量弯曲强度和弹性模量,使用维氏硬度测试评估表面硬度,并且使用原子力显微镜(AFM)评估表面粗糙度,同时使用来研究真菌粘附力和生存力。还分析了唾液衍生生物膜模型中样品的生物膜厚度和生物量。与对照组和ZrO组相比,所有ND-PMMA纳米复合材料组均具有明显更高的平均抗弯强度和统计学上改善的弹性模量(<0.001)。与具有0.3%和0.5%ND的对照组相比,维氏硬度值显着增加(<0.001)。与对照组相比,添加ND还使真菌的黏附力和生存力显着降低(<0.001)。最后,与ZrO组相比,唾液生物膜的形成明显减少。因此,在自聚合的PMMA树脂中加入0.1-0.5 wt。%ND可以显着改善挠曲强度,弹性模量和表面硬度,并提供相当大的抗真菌性。

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