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Mitigation of Ammonia Emissions from Cattle Manure Slurry by Tannins and Tannin-Based Polymers

机译:单宁和单宁基聚合物减轻牛粪浆中氨气的排放

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摘要

With the extensive use of nitrogen-based fertilizer in agriculture, ammonia emissions, especially from cattle manure, are a serious environmental threat for soil and air. The European community committed to reduce the ammonia emissions by 30% by the year 2030 compared to 2005. After a moderate initial reduction, the last report showed no further improvements in the last four years, keeping the 30% reduction a very challenging target for the next decade. In this study, the mitigation effect of different types of tannin and tannin-based adsorbent on the ammonia emission from manure was investigated. Firstly, we conducted a template study monitoring the ammonia emissions registered by addition of the tannin-based powders to a 0.1% ammonia solution and then we repeated the experiments with ready-to-spread farm-made manure slurry. The results showed that all tannin-based powders induced sensible reduction of pH and ammonia emitted. Reductions higher than 75% and 95% were registered for ammonia solution and cattle slurry, respectively, when using flavonoid-based powders. These findings are very promising considering that tannins and their derivatives will be extensively available due to the increasing interest on their exploitation for the synthesis of new-generation “green” materials.
机译:随着氮基肥料在农业中的广泛使用,氨气的排放,特别是牛粪的排放,对土壤和空气构成了严重的环境威胁。欧洲共同体承诺到2030年将氨气排放量与2005年相比减少30%。经过初步的适度减少后,最近的报告显示过去四年中没有进一步的改善,保持30%的减少量是实现该目标的一项非常艰巨的目标。下个十年。在这项研究中,研究了不同类型的单宁和基于单宁的吸附剂对粪便中氨气排放的缓解作用。首先,我们进行了模板研究,以监测通过将单宁粉添加到0.1%氨溶液中记录的氨气排放,然后我们使用现成的农场制成的粪肥进行重复实验。结果表明,所有基于单宁的粉末均能明显降低pH值和释放的氨。当使用基于类黄酮的粉末时,氨溶液和牛粪浆的还原率分别高于75%和95%。考虑到单宁及其衍生物将广泛用于新一代“绿色”材料的合成,因此这些发现非常有希望。

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