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Heterogeneous Ice Nucleation by Soufriere Hills Volcanic Ash Immersed in Water Droplets

机译:Soufriere Hills火山灰浸没在水滴中的异质冰成核

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摘要

Fine particles of ash emitted during volcanic eruptions may sporadically influence cloud properties on a regional or global scale as well as influencing the dynamics of volcanic clouds and the subsequent dispersion of volcanic aerosol and gases. It has been shown that volcanic ash can trigger ice nucleation, but ash from relatively few volcanoes has been studied for its ice nucleating ability. In this study we quantify the efficiency with which ash from the Soufriere Hills volcano on Montserrat nucleates ice when immersed in supercooled water droplets. Using an ash sample from the 11th February 2010 eruption, we report ice nucleating efficiencies from 246 to 265 K. This wide range of temperatures was achieved using two separate droplet freezing instruments, one employing nanolitre droplets, the other using microlitre droplets. Soufriere Hills volcanic ash was significantly more efficient than all other ash samples that have been previously examined. At present the reasons for these differences are not understood, but may be related to mineralogy, amorphous content and surface chemistry.
机译:火山喷发过程中散发出的细小灰尘颗粒可能会在区域或全球范围内偶发地影响云的性质,并影响火山云的动力学以及随后的火山气溶胶和气体的扩散。已经显示出火山灰可以触发冰成核,但是已经研究了来自相对较少的火山灰的冰成核能力。在这项研究中,我们量化了蒙特塞拉特岛Soufriere Hills火山的灰烬浸入过冷水滴中时使冰成核的效率。使用2010年2月11日喷发的灰烬样品,我们报告了246 K至265 K的冰成核效率。使用两台单独的液滴冷冻仪器可达到如此宽的温度范围,其中一种使用纳升液滴,其他使用微升液滴。 Soufriere Hills火山灰比以前检查过的所有其他灰分样品效率更高。目前尚不清楚这些差异的原因,但可能与矿物学,无定形含量和表面化学有关。

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