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SrCrxFe12-xO19 nanoceramics as an effective catalyst for desulfurization of liquid fuels: Green sol-gel synthesis characterization magnetic and optical properties

机译:SrCrxFe12-xO19纳米陶瓷作为液体燃料脱硫的有效催化剂:绿色溶胶-凝胶合成表征磁和光学性质

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摘要

In this work, SrCrxFe12-xO19 (x = 0.0, 0.5, 1.0, 1.5) nanostructures were successfully synthesized by sol-gel auto-combustion method, and different aminoacids were used as green reductants. Various analysis results show that SrCrxFe12-xO19 nanoparticles synthesized successfully.The present study shows that SrCrxFe12-xO19 nanoparticle could be used as adsorbent for the desulfurization of liquid fuels. Increasing of nanoparticles concentration was caused to increase the adsorption rate of sulfur contents of fuel. The adsorption rate of sulfur contents of fuel in various concentrations 4.5, 9.5, and 18.5 g. L -1 of SrCrxFe12-xO19 nanoparticles in solution was estimated about 39, 50, and 62% for 30 min, respectively. The results of catalytic tests reveals that SrCrxFe12-xO19 nanoparticles have the potential to be used as a new kind of semiconductor catalysts for the desulfurization of liquid fuels. Magnetic property of the final sample was measured at room temperature by a vibration sample magnetometer (VSM) and shown that the intrinsic coercivity of product is about 6000 Oe and it exhibits characteristics of single magnetic domains (Mr/ Ms = 0.53).
机译:在这项工作中,SrCrxFe12-xO19(x = 0.0、0.5、1.0、1.5)纳米结构通过溶胶-凝胶自动燃烧法成功合成,并且不同的氨基酸被用作绿色还原剂。各种分析结果表明,SrCrxFe12-xO19纳米颗粒能够成功合成。本研究表明,SrCrxFe12-xO19纳米颗粒可作为液体燃料脱硫的吸附剂。纳米颗粒浓度的增加导致燃料中硫含量的吸附速率增加。各种浓度的4.5、9.5和18.5 g燃料对硫含量的吸附速率。 SrCrxFe12-xO19纳米粒子在溶液中30分钟的L -1 分别约为39%,50%和62%。催化测试的结果表明,SrCrxFe12-xO19纳米粒子具有用作液体燃料脱硫的新型半导体催化剂的潜力。最终样品的磁性能在室温下通过振动样品磁力计(VSM)进行测量,结果表明产品的固有矫顽力约为6000 Oe,并且表现出单个磁畴(Mr / M s = 0.53)。

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