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Reference Correlations for the Viscosity and Thermal Conductivity of n-Undecane

机译:正十一烷的粘度和导热系数的参考相关性

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摘要

This paper presents new wide-ranging correlations for the viscosity and thermal conductivity of n-undecane based on critically evaluated experimental data. The correlations are designed to be used with a recently published equation of state that is valid from the triple point to 700 K, at pressures up to 500 MPa, with densities below 776.86 kg m−3. The estimated uncertainty for the dilute-gas viscosity is 2.4%, and the estimated uncertainty for viscosity in the liquid phase for pressures up to 60 MPa over the temperature range 260 K to 520 K is 5%. The estimated uncertainty is 3% for the thermal conductivity of the low-density gas, and 3% for the liquid over the temperature range from 284 K to 677 K at pressures up to 400 MPa. Both correlations behave in a physically reasonable manner when extrapolated to the full range of the equation of state, however care should be taken when using the correlations outside of the validated range. The uncertainties will be larger outside of the validated range, and also in the critical region.
机译:本文基于严格评估的实验数据,提出了正十一烷的粘度和导热系数的广泛相关性。该相关关系被设计为与最近发布的状态方程一起使用,该状态方程在压力高达500 MPa,密度低于776.86 kg m -3 的情况下,从三点到700 K有效。稀气体粘度的估计不确定度为2.4%,在260 K至520 K的温度范围内,压力高达60 MPa时液相粘度的估计不确定度为5%。在284 K至677 K的温度范围内,压力高达400 MPa时,低密度气体的导热系数估计为3%,液体的不确定度为3%。当推断状态方程的整个范围时,这两种相关关系在物理上都表现得合理,但是在验证范围之外使用这些相关关系时,应格外小心。在验证范围之外以及在关键区域中,不确定性将更大。

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