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Engineering optical properties of gold-coated nanoporous anodic alumina for biosensing

机译:涂金纳米多孔阳极氧化铝的生物工程光学性能

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摘要

The effect in the Fabry-Pérot optical interferences of nanoporous anodic alumina films coated with gold is studied as a function of the porosity and of the gold thickness by means of reflectance spectroscopy. Samples with porosities between 14 and 70% and gold thicknesses (10 and 20 nm) were considered. The sputtering of gold on the nanoporous anodic alumina (NAA) films results in an increase of the fringe intensity of the oscillations in the spectra resulting from Fabry-Pérot interferences in the porous layer, with a reduction in the maximum reflectance in the UV-visible region. For the thicker gold layer, sharp valleys appear in the near-infrared (IR) range that can be useful for accurate spectral shift measurements in optical biosensing. A theoretical model for the optical behavior has also been proposed. The model shows a very good agreement with the experimental measurements, what makes it useful for design and optimization of devices based on this material. This material capability is enormous for using it as an accurate and sensitive optical sensor, since gold owns a well-known surface chemistry with certain molecules, most of them biomolecules.
机译:通过反射光谱法研究了金包覆的纳米多孔阳极氧化铝膜在法布里-珀罗光学干涉中的作用,该作用与孔隙率和金厚度有关。考虑孔隙率在14%到70%之间且金的厚度(10到20 nm)的样品。纳米多孔阳极氧化铝(NAA)膜上的金溅射导致多孔层中的Fabry-Pérot干涉产生的光谱振荡的条纹强度增加,而紫外可见光的最大反射率降低区域。对于较厚的金层,在近红外(IR)范围内会出现尖锐的波谷,这对于光学生物传感中的准确光谱偏移测量非常有用。还提出了光学行为的理论模型。该模型与实验测量结果非常吻合,这使其对于基于该材料的设备设计和优化非常有用。这种材料的能力对于将其用作精确而灵敏的光学传感器而言是巨大的,因为金拥有众所周知的具有某些分子的表面化学,其中大多数是生物分子。

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