Efficient p-type dye-sensitized solar cells with all-nano-electrodes: NiCo2S4 mesoporous nanosheet counter electrodes directly converted from NiCo2O4 photocathodes

摘要

We report the successful growth of NiCo2S4 nanosheet films converted from NiCo2O4 nanosheet films on fluorine-doped tin oxide substrates by a low-temperature solution process. Low-cost NiCo2S4 and NiCo2O4 nanosheet films were directly used for replacing conventional Pt and NiO as counter electrodes and photocathodes, respectively, to construct all-nano p-type dye-sensitized solar cells (p-DSSCs) with high performance. Compared to Pt, NiCo2S4 showed higher catalytic activity towards the I^-/I3^- redox in electrolyte, resulting in an improved photocurrent density up to 2.989 mA/cm², which is the highest value in reported p-DSSCs. Present p-DSSCs demonstrated a cell efficiency of 0.248 % that is also comparable with typical NiO-based p-DSSCs.