Hydrothermal-assisted exfoliation of Y/Tb/Eu ternary layered rare-earth hydroxides into tens of micron-sized unilamellar nanosheets for highly oriented and color-tunable nano-phosphor films

摘要

Efficient exfoliation of well-crystallized (Y0.96TbxEu0.04-x)2(OH)5NO3 · nH2O (0 ≤ x ≤ 0.04) layered rare-earth hydroxide (LRH) crystals into tens of micron-sized unilamellar nanosheets has been successfully achieved by inserting water insoluble oleate anions (C17H33COO⁻) into the interlayer of the LRH via hydrothermal anion exchange at 120°C, followed by delaminating in toluene. The intercalation of oleate anions led to extremely expanded interlayer distances (up to approximately 5.2 nm) of the LRH crystals and accordingly disordered stacking of the ab planes along the c-axis and also weakened interlayer interactions, without significantly damaging the ab plane. As a consequence, the thickness of the LRH crystals increased from approximately 1 to 10 μm, exhibiting a behavior similar to that observed from the smectite clay in water. Highly [111]-oriented and approximately 100-nm thick oxide films of >(Y0.96TbxEu0.04-x>)2O3 (0 ≤ x ≤ 0.04) have been obtained through spin-coating of the exfoliated colloidal nanosheets on quartz substrate, followed by annealing at 800°C. Upon UV excitation at 266 nm, the oxide transparent films exhibit bright luminescence, with the color-tunable emission from red to orange, yellow, and then green by increasing the Tb³⁺ content from x = 0 to 0.04.Electronic supplementary materialThe online version of this article (doi:10.1186/s11671-015-0828-0) contains supplementary material, which is available to authorized users.