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Synthesis Characterization and Microwave Absorption Properties of Reduced Graphene Oxide/Strontium Ferrite/Polyaniline Nanocomposites

机译:还原氧化石墨烯/锶铁氧体/聚苯胺纳米复合材料的合成表征和微波吸收性能

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摘要

Strontium ferrite nanoparticles were prepared by a coprecipitation method, and reduced graphene oxide/strontium ferrite/polyaniline (R-GO/SF/PANI) ternary nanocomposites were prepared by in situ polymerization method. The morphology, structure, and magnetic properties of the ternary nanocomposites were investigated by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), TEM, Raman, and VSM. The microwave-absorbing properties of the composites were measured by a vector network analyzer. The XRD patterns show the single phase of strontium hexaferrite without other intermediate phases. TEM photographs reveal that strontium ferrite nanoparticles are uniformly dispersed on the surfaces of R-GO sheets. The R-GO/SF/PANI nanocomposite exhibited the best absorption property with the optimum matching thickness of 1.5 mm in the frequency of 2–18 GHz. The value of the maximum RL was −45.00 dB at 16.08 GHz with the 5.48-GHz bandwidth. The excellent absorption properties of R-GO/SF/PANI nanocomposites indicated their great potential as microwave-absorbing materials.
机译:共沉淀法制备锶铁氧体纳米粒子,原位聚合法制备还原型氧化石墨烯/锶铁氧体/聚苯胺(R-GO / SF / PANI)三元纳米复合材料。通过X射线粉末衍射(XRD),傅立叶变换红外光谱(FT-IR),TEM,拉曼和VSM研究了三元纳米复合材料的形态,结构和磁性。用矢量网络分析仪测量复合材料的微波吸收性能。 X射线衍射图谱显示了六价锶铁氧体的单相,而没有其他中间相。 TEM照片显示锶铁氧体纳米颗粒均匀地分散在R-GO片的表面上。 R-GO / SF / PANI纳米复合材料在2-18 GHz的频率下表现出最佳的吸收性能,最佳匹配厚度为1.5mm。在16.08 GHz和5.48 GHz带宽下,最大RL值为-45.00 dB。 R-GO / SF / PANI纳米复合材料的优异吸收性能表明其作为微波吸收材料的巨大潜力。

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