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A robust melting class bulk superhydrophobic material with heat-healing and self-cleaning properties

机译:具有热修复和自清洁特性的坚固的熔融类大块超疏水材料

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摘要

Superhydrophobic (SH) materials are essential for a myriad of applications such as anti-icing and self-cleaning due to their extreme water repellency. A single, robust material simultaneously possessing melt-coatability, bulk water repellency, self-cleanability, self-healability, self-refreshability, and adhesiveness has been remaining an elusive goal. We demonstrate a unique class of melt-processable, bulk SH coating by grafting long alkyl chains on silica nanoparticle surface by a facile one-step method. The well-defined nanomaterial shows SH property in the bulk and is found to heal macro-cracks on gentle heating. It retains wettability characteristics even after abrading with a sand paper. The surface regenerates SH features (due to reversible self-assembly of nano structures) quickly at ambient temperature even after cyclic water impalement, boiling water treatment and multiple finger rubbing tests. It exhibits self-cleaning properties on both fresh and cut surfaces. This kind of coating, hitherto undisclosed, is expected to be a breakthrough in the field of melt-processable SH coatings.
机译:超疏水(SH)材料由于具有极高的防水性,因此对于诸如防冰和自清洁之类的众多应用至关重要。同时具有熔融涂覆性,疏水性,自清洁性,自修复性,自刷新性和粘合性的单一,坚固的材料仍然是难以实现的目标。我们展示了一类独特的可熔融加工的整体SH涂层,它通过一种简便的一步法将长烷基链接枝在二氧化硅纳米颗粒表面上。定义明确的纳米材料在整体上显示出SH特性,并发现在温和加热下可以治愈宏观裂纹。即使用砂纸研磨后,它仍保持可湿性。即使在循环水刺穿,沸水处理和多指摩擦测试之后,该表面在环境温度下仍可快速再生SH特性(由于纳米结构的可逆自组装性)。它在新鲜表面和切割表面上均具有自清洁性能。迄今为止尚未公开的这种涂料有望成为可熔融加工SH涂料领域的突破。

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