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CoCO3 from one-step micro-emulsion method as electrode materials for Faradaic capacitors

机译:一步微乳液法制备的CoCO3作为法拉第电容器的电极材料

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摘要

Faradaic capacitor (FC) has been widely investigated during the past few decades, and dozens of prototypes have been proposed. However, it has not reached its full potential. In this work, we demonstrate a kind of FC comprising of a CoCO3 electrode. Synthesized through a micro-emulsion route, such CoCO3 shows low crystallinity and porous wool-ball structures stacked by needle-like individuals. It shows desirable electrochemical properties in terms of excellent high-rate performance and high reversibility. Also, it could deliver a capacitance of 440 F·g−1 at 1 A·g−1, and shows no capacitance decay after 1000 cycles. Since metal carbonate is capable of delivering good electrochemical performances and its preparation is easier and more cost-efficient, it should be a feasible candidate for electrode material of FC.
机译:在过去的几十年中,对法拉第电容器(FC)进行了广泛的研究,并提出了数十个原型。但是,它尚未充分发挥潜力。在这项工作中,我们演示了一种由CoCO3电极组成的FC。通过微乳化途径合成的此类CoCO3显示出低结晶度和由针状个体堆叠的多孔羊毛球结构。就优异的高速率性能和高可逆性而言,它显示出所需的电化学性能。而且,它在1 A·g -1 时可提供440 F·g -1 的电容,并且在1000次循环后无电容衰减。由于金属碳酸盐能够提供良好的电化学性能,并且其制备更容易且更具成本效益,因此它应该是FC电极材料的可行选择。

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