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Role of the particle size polydispersity in the electrical conductivity of carbon nanotube-epoxy composites

机译:粒径多分散度在碳纳米管-环氧树脂复合材料电导率中的作用

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摘要

Carbon nanotubes (CTNs) with large aspect-ratios are extensively used to establish electrical connectedness in polymer melts at very low CNT loadings. However, the CNT size polydispersity and the quality of the dispersion are still not fully understood factors that can substantially alter the desired characteristics of CNT nanocomposites. Here we demonstrate that the electrical conductivity of polydisperse CNT-epoxy composites with purposely-tailored distributions of the nanotube length L is a quasiuniversal function of the first moment of L. This finding challenges the current understanding that the conductivity depends upon higher moments of the CNT length. We explain the observed quasiuniversality by a combined effect between the particle size polydispersity and clustering. This mechanism can be exploited to achieve controlled tuning of the electrical transport in general CNT nanocomposites.
机译:具有宽高比的碳纳米管(CTN)被广泛用于在非常低的CNT负载下在聚合物熔体中建立电连接性。然而,仍不能完全理解CNT尺寸的多分散性和分散体的质量,这些因素可以实质上改变CNT纳米复合材料的所需特性。在这里,我们证明了纳米管长度L有针对性地分布的多分散CNT-环氧树脂复合材料的电导率是L的第一矩的准通用函数。这一发现对当前的理解提出挑战,即电导率取决于CNT的更高矩长度。我们通过粒度多分散性和聚类之间的综合作用解释了观测到的准大学。可以利用这种机制来实现一般CNT纳米复合材料中电传输的受控调节。

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