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Investigation of Phosphate Removal Capability of Blast Furnace Slag in Wastewater Treatment

机译:高炉渣处理废水除磷能力的研究。

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摘要

Blast Furnace Slag (BFS) is a by-product of iron making with a potential to be used in different applications. In this research, BFS is used to investigate the phosphate removal ability in wastewater. BFS has the required concentrations of surface calcium to potentially precipitate phosphate from wastewater. Removal of phosphate from wastewater depends on variety of conditions, such as the size of BFS particles, adsorbent dose, contact time and pH. The conditions responsible for phosphate removal from wastewater with BFS were analysed and the phosphate removal capacity optimised according to the BFS chemical content. The results in this work demonstrated that the basicity (CaO/SiO2) of BFS has a reverse effect on phosphate removal capacity. High basicity reduces the capability of BFS for removal of phosphate. BFS composition before and after phosphate removal was determined with Energy Dispersive Spectroscopy (EDS), Fourier Transfer Infrared Spectroscopy (FTIR) and UV-Vis spectrophotometry. The results revealed that the slag samples added varying concentrations of trace metals Al, Cd, Co and Hg into the treated water, which will need to be further conditioned by dilution with unpolluted water or other treatments before disposal or re-use.
机译:高炉矿渣(BFS)是炼铁的副产品,有可能在不同的应用中使用。在这项研究中,BFS用于研究废水中的磷酸盐去除能力。 BFS具有所需的表面钙浓度,以可能从废水中沉淀出磷酸盐。从废水中去除磷酸盐取决于多种条件,例如BFS颗粒的大小,吸附剂剂量,接触时间和pH。分析了使用BFS从废水中去除磷酸盐的条件,并根据BFS化学含量优化了磷酸盐去除能力。这项工作的结果表明,BFS的碱度(CaO / SiO2)对除磷能力有相反的影响。高碱性会降低BFS去除磷酸盐的能力。用能量分散光谱仪(EDS),傅里叶转移红外光谱仪(FTIR)和UV-Vis分光光度法测定磷酸盐去除前后的BFS组成。结果表明,炉渣样品向处理后的水中添加了不同浓度的痕量金属Al,Cd,Co和Hg,在处理或重新使用之前,需要通过用未污染的水稀释或其他处理来进一步处理。

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