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Phase equilibrium in Mg-Cu-Y

机译:Mg-Cu-Y中的相平衡

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摘要

Magnesium-based bulk metallic glasses (BMG) have potential in applications ranging from biomedical to sports equipment and the Mg-Cu-Y system offers some of the most promising alloys. Phase relations and ternary solubility of the binary and ternary compounds of this system have been experimentally investigated. The Isothermal section of Mg-Cu-Y system at 673 K for the entire composition range has been constructed. Phase relations in the Cu-rich (>66 at.% Cu) region of the Mg-Cu-Y system has been determined for the first time. The homogeneity range of three ternary compounds has been determined. Solidifications behavior of several key alloys have been discussed based on the differential scanning calorimetry (DSC) experiments and thermodynamic calculations. Extensive analysis of the DSC curves has been carried out to relate them to the corresponding phase transformation reactions and temperatures. Some of the most promising metallic glass forming regions have been analyzed using thermodynamic calculations.
机译:镁基块状金属玻璃(BMG)在从生物医学到运动器材的广泛应用中具有潜力,而Mg-Cu-Y系统提供了一些最有前途的合金。已经通过实验研究了该系统的二元和三元化合物的相关系和三元溶解度。在整个成分范围内,Mg-Cu-Y系统的等温截面为673K。首次确定了Mg-Cu-Y系统的富Cu(> 66 at。%Cu)区域中的相位关系。已经确定了三种三元化合物的均一性范围。基于差示扫描量热法(DSC)实验和热力学计算,已经讨论了几种关键合金的凝固行为。已经对DSC曲线进行了广泛的分析,以将它们与相应的相变反应和温度相关联。使用热力学计算已经分析了一些最有希望的金属玻璃形成区域。

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