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Dual Conical Conducting Filament Model in Resistance Switching TiO2 Thin Films

机译:电阻切换TiO2薄膜中的双锥形导电丝模型

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摘要

The resetting behaviors of Pt/TiO2/Pt resistive switching (RS) cell in unipolar RS operations were studied in detail through an experiment and by modeling. The experiment showed that the apparently highly arbitrary resetting current-voltage (I–V) curves could be grouped into three types: normal, delayed, and abnormal behaviors. A dual conical conducting filament (CF) model was conceived, and their electrothermal behaviors were analytically described from the heat-balance and charge-transport equations. The almost spontaneous resetting behavior of the normal reset could be easily understood from the mutually constructive interference effect between the Joule heating and temperature-dependent resistance effect along the CF. The delayed reset could be explained by the time-dependent increase in the reset voltage during the rest process, which was most probably induced in the more conical-shaped CF. The abnormal reset could be understood from the temporal transfer of oxygen ions near the kink positions of the two different-diameter portions of the more cylindrical CFs, which temporally decreases the overall resistance immediately prior for the actual reset to occur. The accuracy of the dual conical CF model was further confirmed by adopting a more thorough electrothermal simulation package, COMSOL.
机译:通过实验和建模,详细研究了Pt / TiO2 / Pt电阻转换(RS)电池在单极RS操作中的复位行为。实验表明,看似高度任意的复位电流-电压(IV)曲线可分为三种类型:正常,延迟和异常行为。构想了一个双锥形导电丝(CF)模型,并根据热平衡和电荷传输方程对它们的电热行为进行了分析描述。从焦耳加热和沿着CF的温度相关电阻效应之间的相互建设性干涉效应,可以很容易地理解正常复位的几乎自发的复位行为。延迟的复位可以用休息过程中复位电压随时间的增加来解释,这很可能是在圆锥形CF中引起的。从更多圆柱形CF的两个不同直径部分的扭结位置附近的氧离子的时间转移可以理解异常复位,这在即将发生实际复位之前会暂时降低总电阻。通过采用更详尽的电热仿真程序包COMSOL,进一步证实了双锥形CF模型的准确性。

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