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Silver nanowires decorated with silver nanoparticles for low-haze flexible transparent conductive films

机译:用纳米银装饰的银纳米线用于低雾度柔性透明导电膜

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摘要

Silver nanowires have attracted much attention for use in flexible transparent conductive films (TCFs) due to their low sheet resistance and flexibility. However, the haze was too high for replacing indium-tin-oxide in high-quality display devices. Herein, we report flexible TCFs, which were prepared using a scalable bar-coating method, with a low sheet resistance (24.1 Ω/sq at 96.4% transmittance) and a haze (1.04%) that is comparable to that of indium-tin-oxide TCFs. To decrease the haze and maintain a low sheet resistance, small diameter silver nanowires (~20 nm) were functionalized with low-temperature surface-sintering silver nanoparticles (~5 nm) using bifunctional cysteamine. The silver nanowire-nanoparticle ink stability was excellent. The sheet resistance of the TCFs was decreased by 29.5% (from 34.2 to 24.1 Ω/sq) due to the functionalization at a low curing temperature of 85 °C. The TCFs were highly flexible and maintained their stability for more than 2 months and 10,000 bending cycles after coating with a protective layer.
机译:银纳米线由于其低的薄层电阻和柔韧性而引起了在柔性透明导电膜(TCF)中的使用的广泛关注。然而,雾度太高以至于不能代替高质量显示装置中的氧化铟锡。在此,我们报告了使用可扩展的棒涂法制备的柔性TCF,其薄层电阻低(透射率96.4%时为24.1ΩΩ/ sq),雾度(1.04%)与铟锡锡相当。氧化物TCF。为了降低雾度并保持较低的薄层电阻,使用双功能半胱胺将小直径银纳米线(〜20 nm)与低温表面烧结银纳米颗粒(〜5 nm)官能化。银纳米线-纳米粒子油墨的稳定性优异。由于在85 C的低固化温度下进行了功能化,TCF的薄层电阻降低了29.5%(从34.2降至24.1Ω/ sq)。 TCF具有高度的柔韧性,并在涂覆保护层后保持其稳定性超过2个月,并弯曲10,000次。

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