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Solvent-Free Manufacturing of Electrodes for Lithium-ion Batteries

机译:锂离子电池电极的无溶剂生产

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摘要

Lithium ion battery electrodes were manufactured using a new, completely dry powder painting process. The solvents used for conventional slurry-cast electrodes have been completely removed. Thermal activation time has been greatly reduced due to the time and resource demanding solvent evaporation process needed with slurry-cast electrode manufacturing being replaced by a hot rolling process. It has been found that thermal activation time to induce mechanical bonding of the thermoplastic polymer to the remaining active electrode particles is only a few seconds. Removing the solvent and drying process allows large-scale Li-ion battery production to be more economically viable in markets such as automotive energy storage systems. By understanding the surface energies of various powders which govern the powder mixing and binder distribution, bonding tests of the dry-deposited particles onto the current collector show that the bonding strength is greater than slurry-cast electrodes, 148.8 kPa as compared to 84.3 kPa. Electrochemical tests show that the new electrodes outperform conventional slurry processed electrodes, which is due to different binder distribution.
机译:锂离子电池电极采用全新的完全干粉喷涂工艺制造。用于常规浆料浇铸电极的溶剂已被完全去除。由于用浆浇铸电极制造所需的时间和资源要求很高的溶剂蒸发工艺被热轧工艺所取代,因此大大缩短了热活化时间。已经发现,引起热塑性聚合物机械粘合到剩余的活性电极颗粒上的热活化时间仅为几秒钟。去除溶剂和干燥过程可以使大规模锂离子电池生产在诸如汽车储能系统等市场上更加经济可行。通过了解控制粉末混合和粘合剂分布的各种粉末的表面能,干法沉积颗粒在集流体上的结合测试表明,结合强度比浆料浇铸电极高,为88.8 kPa,为148.8 kPa。电化学测试表明,由于不同的粘合剂分布,新电极的性能优于传统的浆料处理电极。

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