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Limited Quantum Helium Transportation through Nano-channels by Quantum Fluctuation

机译:通过量子涨落限制通过纳米通道的量子氦运输。

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摘要

Helium at low temperatures has unique quantum properties such as superfluidity, which causes it to behave differently from a classical fluid. Despite our deep understanding of quantum mechanics, there are many open questions concerning the properties of quantum fluids in nanoscale systems. Herein, the quantum behavior of helium transportation through one-dimensional nanopores was evaluated by measuring the adsorption of quantum helium in the nanopores of single-walled carbon nanohorns and AlPO4-5 at 2–5 K. Quantum helium was transported unimpeded through nanopores larger than 0.7 nm in diameter, whereas quantum helium transportation was significantly restricted through 0.4-nm and 0.6-nm nanopores. Conversely, nitrogen molecules diffused through the 0.4-nm nanopores at 77 K. Therefore, quantum helium behaved as a fluid comprising atoms larger than 0.4–0.6 nm. This phenomenon was remarkable, considering that helium is the smallest existing element with a (classical) size of approximately 0.27 nm. This finding revealed the presence of significant quantum fluctuations. Quantum fluctuation determined the behaviors of quantum flux and is essential to understanding unique quantum behaviors in nanoscale systems.
机译:低温下的氦具有独特的量子特性,例如超流动性,这使它的行为不同于传统流体。尽管我们对量子力学有深入的了解,但是关于纳米级系统中量子流体的性质仍有许多悬而未决的问题。在此,通过测量单壁碳纳米角和AlPO4-5在2–5 K下的氦吸附量,评估了氦通过一维纳米孔传输的量子行为。直径为0.7?nm,而通过0.4-nm和0.6-nm纳米孔显着限制了量子氦的传输。相反,氮分子在77 K处通过0.4 nm的纳米孔扩散,因此,量子氦表现为一种流体,其中包含的原子大于0.4-0.6 nm。考虑到氦是现存的最小元素,其(经典)尺寸约为0.27 nm,因此这种现象非常明显。这一发现表明存在明显的量子波动。量子涨落决定了量子通量的行为,对于理解纳米级系统中独特的量子行为至关重要。

著录项

  • 期刊名称 Scientific Reports
  • 作者

    Tomonori Ohba;

  • 作者单位
  • 年(卷),期 -1(6),-1
  • 年度 -1
  • 页码 28992
  • 总页数 10
  • 原文格式 PDF
  • 正文语种
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