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Two-Dimensional rGO-MoS2 Hybrid Additives for High-Performance Magnetorheological Fluid

机译:高性能磁流变液的二维rGO-MoS2杂化添加剂

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摘要

Magnetorheological fluids (MRF) that undergo a change in their viscoelastic properties under the magnetic fields have been considered as one of most important smart functional materials for vibration dampers and shock absorbers in several engineering applications. However, the use of magnetorheological fluids in practical applications has been limited by poor sedimentation ratio and on-state yield stress. Herein, we report hybrid rGO-MoS2 additives for a high-performance magnetorheological fluid. Two different kinds of hybrid additives, which are called non-magnetic rGO-MoS2 and magnetic Fe-rGO-MoS2, were synthesized by using a hydrothermal method. The rGO-MoS2 added suspensions remained stable for the first 90 min whereas the CIP MRFs settled down quickly (65%) in the first 10 minutes. The Fe-rGO-MoS2 additives showed a 24% higher on-state shear stress as compared to CIP MRFs. On the other hand, an increase of 60% in the on-state yield stress for Fe-rGO-MoS2 MRF can be attributed to the gap-filling by the hybrid additives during columnar-structure formation. Among two-dimensional (2D) materials, Molybdenum Disulphide (MoS2) is a member of transition metal dichalcogenides (TMDCs), traditionally used as solid lubricant, while reduced graphene-oxide (rGO) is a well-known 2D material with supreme mechanical properties. We believe that this study will blaze the new way for developing a high-performance magnetorheological fluids based on various 2D material hybrids.
机译:在磁场下经历了粘弹性变化的磁流变流体(MRF)被认为是在一些工程应用中用于减振器和减震器的最重要的智能功能材料之一。但是,磁流变流体在实际应用中的使用受到沉降率和导通屈服应力差的限制。在此,我们报告了用于高性能磁流变液的混合rGO-MoS2添加剂。利用水热法合成了两种不同的杂化添加剂,分别称为非磁性rGO-MoS2和磁性Fe-rGO-MoS2。在最初的90分钟内,添加rGO-MoS2的悬浮液保持稳定,而在最初的10分钟内,CIP MRF迅速沉降(65%)。与CIP MRF相比,Fe-rGO-MoS2添加剂的状态剪切应力高24%。另一方面,Fe-rGO-MoS2 MRF的导通状态屈服应力增加60%可以归因于混合添加剂在柱状结构形成过程中的间隙填充。在二维(2D)材料中,二硫化钼(MoS2)是过渡金属二硫化碳(TMDC)的成员,传统上用作固体润滑剂,而氧化石墨烯(rGO)是众所周知的具有出色机械性能的2D材料。 。我们相信,这项研究将开辟一种基于各种2D材料混合材料开发高性能磁流变流体的新方法。

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