首页> 美国卫生研究院文献>Nature Communications >Stretched and compressed exponentials in the relaxation dynamics of a metallic glass-forming melt
【2h】

Stretched and compressed exponentials in the relaxation dynamics of a metallic glass-forming melt

机译:金属玻璃熔体的弛豫动力学中的拉伸和压缩指数

代理获取
本网站仅为用户提供外文OA文献查询和代理获取服务,本网站没有原文。下单后我们将采用程序或人工为您竭诚获取高质量的原文,但由于OA文献来源多样且变更频繁,仍可能出现获取不到、文献不完整或与标题不符等情况,如果获取不到我们将提供退款服务。请知悉。

摘要

The dynamics of glass-forming systems shows a multitude of features that are absent in normal liquids, such as non-exponential relaxation and a strong temperature-dependence of the relaxation time. Connecting these dynamic properties to the microscopic structure of the system is challenging because of the presence of the structural disorder. Here we use computer simulations of a metallic glass-former to establish such a connection. By probing the temperature and wave-vector dependence of the intermediate scattering function we find that the relaxation dynamics of the glassy melt is directly related to the local arrangement of icosahedral structures: Isolated icosahedra give rise to a liquid-like stretched exponential relaxation whereas clusters of icosahedra lead to a compressed exponential relaxation that is reminiscent to the one found in a solid. Our results show that in metallic glass-formers these two types of relaxation processes can coexist and give rise to a dynamics that is surprisingly complex.
机译:玻璃形成系统的动力学表现出正常液体中不存在的许多特征,例如非指数弛豫和弛豫时间的强烈温度依赖性。由于存在结构紊乱,将这些动态特性连接到系统的微观结构具有挑战性。在这里,我们使用金属玻璃成型机的计算机模拟来建立这种连接。通过研究温度和波矢量对中间散射函数的依赖性,我们发现玻璃状熔体的弛豫动力学与二十面体结构的局部排列直接相关:孤立的二十面体产生了液体状的拉伸指数弛豫,而簇状的二十面体导致压缩的指数松弛,让人联想到固体中的松弛。我们的结果表明,在金属玻璃成型机中,这两种类型的松弛过程可以共存并产生令人惊讶地复杂的动力学。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
代理获取

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号